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Additive Differential Double Pulse Voltammetry Applied to the Study of Multistep Electron Transfer Reactions with Microelectrodes of Different Geometries

Abstract:

Additive differential double pulse voltammetry (ADDPV) is applied to the study of reversible multistep electron transfers at microelectrodes of different geometries, including discs, (hemi)spheres, bands and cylinders. Analytical expressions are deduced for arbitrary numbers of electrons transferred and for any difference between the formal potentials of the different redox couples. ADDPV curves show two or more peaks and one or more crossing potentials depending on the number of steps, the d...

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Publication status:
Published

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Authors


Gonzalez, J More by this author
Laborda, E More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume:
7
Issue:
7
Pages:
5765-5778
Publication date:
2012-07-05
EISSN:
1452-3981
ISSN:
1452-3981
URN:
uuid:99332662-c5bd-4f1a-a44c-f4638905e4d5
Source identifiers:
344543
Local pid:
pubs:344543

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