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Heavy water hydration of mannose: the anomeric effect in solvation, laid bare

Abstract:

The presence and consequences of the anomeric effect have been explored and directly exposed, through an investigation of the vibrational spectroscopy of the doubly and triply hydrated a and b anomers of phenyl D-mannopyranoside, (PhMan) isolated under molecular beam conditions in the gas phase. The experiments have been aided by the simple trick of substituting D2O for H2O, which has the advantage of isotopically isolating the carbohydrate (OH) bands from the water (OD) bands. Recording the ...

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Publication status:
Published

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Publisher copy:
10.1039/c1sc00002k

Authors


Mayorkas, N More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Simons, JP More by this author
Journal:
CHEMICAL SCIENCE
Volume:
2
Issue:
6
Pages:
1128-1134
Publication date:
2011
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
URN:
uuid:98f2e2ec-b42a-409a-8cba-0d6dc030a820
Source identifiers:
146717
Local pid:
pubs:146717
Language:
English

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