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Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).

Abstract:

A combined structural/EPR/computational chemistry investigation is reported on the two paramagnetic hydrido-cluster salts [Rh(6)(PCy(3))(6)H(12)][BAr(F)(4)] and [Rh(6)(PCy(3))(6)H(14)][BAr(F)(4)], the latter being formed by reversible addition of H(2) to the former, [BAr(F)(4)](-) = [B{C(6)H(3)(CF(3))(2)}(4)](-). The solid-state structure of [Rh(6)(PCy(3))(6)H(14)][BAr(F)(4)] shows an expanded cluster core compared to previously reported [Rh(6)(PCy(3))(6)H(12)][BAr(F)(4)] indicative of the ad...

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Publication status:
Published

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Publisher copy:
10.1039/b919209c

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
39
Issue:
7
Pages:
1726-1733
Publication date:
2010-02-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:9865b0bd-2597-42f3-909e-8b89275302bb
Source identifiers:
49040
Local pid:
pubs:49040

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