- Abstract:
-
A combined structural/EPR/computational chemistry investigation is reported on the two paramagnetic hydrido-cluster salts [Rh(6)(PCy(3))(6)H(12)][BAr(F)(4)] and [Rh(6)(PCy(3))(6)H(14)][BAr(F)(4)], the latter being formed by reversible addition of H(2) to the former, [BAr(F)(4)](-) = [B{C(6)H(3)(CF(3))(2)}(4)](-). The solid-state structure of [Rh(6)(PCy(3))(6)H(14)][BAr(F)(4)] shows an expanded cluster core compared to previously reported [Rh(6)(PCy(3))(6)H(12)][BAr(F)(4)] indicative of the ad...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b919209c
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Volume:
- 39
- Issue:
- 7
- Pages:
- 1726-1733
- Publication date:
- 2010-02-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:9865b0bd-2597-42f3-909e-8b89275302bb
- Source identifiers:
-
49040
- Local pid:
- pubs:49040
- Language:
- English
- Keywords:
- Copyright date:
- 2010
Journal article
Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).
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