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THE APPLICATION OF INSITU ELECTROCHEMICAL ELECTRON-SPIN-RESONANCE TO EC AND ECE PROCESSES - THE REDUCTION OF 2-NITROPROPANE

Abstract:

Radical intermediates may be generated at a channel electrode located within an ESR cavity. Theory describing the ESR signal-flow rate-current behaviour for EC and ECE processes is given where the chemical step is assumed to be first-order. An analytical expression for the current-flow rate variation for an ECE process at a channel electrode is also given. Experiments carried out on the reduction of 2-nitropropane at mercury electrodes in the pH range 8.6-10.5 are described. ESR signals due t...

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Publication status:
Published

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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
161
Issue:
1
Pages:
129-145
Publication date:
1984-01-01
DOI:
ISSN:
0022-0728
URN:
uuid:967cb87c-6e35-4224-ae6a-132c1e714e23
Source identifiers:
52932
Local pid:
pubs:52932
Language:
English

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