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Organotin Dithiocarbamates: Single-Source Precursors for Tin Sulfide Thin Films by Aerosol-Assisted Chemical Vapor Deposition (AACVD)

Abstract:

A series of diorganotin complexes of dithiocarbamates [Sn(C 4H9)2(S2CN(RR′) 2)2] (R, R′ = ethyl (1); R = methyl, R′ = butyl (2); R, R′ = butyl (3); R = methyl, R′ = hexyl (4); and [Sn(C6H5)2(S2CN(RR′) 2)2] (R, R′ = ethyl (5); R = methyl, R′ = butyl (6); R, R′ = butyl (7); R = methyl, R′ = hexyl (8) were synthesized. Single-crystal X-ray structures of 2, 3, and 8 were determined. Thermogravimetric analysis (TGA) showed single-step decomposition for the complexes 1, 3, and 5-8, and double-step ...

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Publication status:
Published

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Publisher copy:
10.1021/cm301660n

Authors


Ramasamy, K More by this author
Kuznetsov, VL More by this author
Raftery, J More by this author
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Journal:
CHEMISTRY OF MATERIALS
Volume:
25
Issue:
3
Pages:
266-276
Publication date:
2013-02-12
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
URN:
uuid:9636fcfd-ab3e-4cf9-b7fa-00f94cb92d6c
Source identifiers:
388163
Local pid:
pubs:388163

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