The transition metal-directed self-assembly of dithiocarbamate ligand functionalized upper and lower rim calixarenes affords novel dimeric bimetallic bis(calixarene) species as determined by a combination of analytical methods including X-ray crystallography. An exception is a zinc(II) dithiocarbamate upper rim calixarene assembly which is monomeric in nature. Electrochemical investigations reveal the bimetallic copper(II) bis(calixarene) systems can electrochemically sense dihydr...Expand abstract
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Transition metal-directed self-assembly of calixarene based dithiocarbamate ligands.
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