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Structural investigation on lead fluoride-lithium fluoride at various compositions and temperatures

Abstract:

Local structure around lead ion of molten PbF2-LiF system at various compositions (xPbF2=0.2, 0.4, 0.6, 0.8 and 1.0) were investigated by extended X-ray absorption fine structure (EXAFS) analysis, and composition dependence of the local structure was revealed. Coordination number and inter-ionic distance between 1st neighboring Pb2+-F- show similar to each other except at eutectic composition. In addition, structural change observed in EXAFS signals of pure PbF2 is reproduced by molecular dyn...

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Publication status:
Published

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Publisher copy:
10.1016/j.jnucmat.2005.04.025

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
Journal:
JOURNAL OF NUCLEAR MATERIALS More from this journal
Volume:
344
Issue:
1-3
Pages:
104-108
Publication date:
2005-09-01
DOI:
ISSN:
0022-3115
Language:
English
Pubs id:
pubs:369757
UUID:
uuid:95952248-78c4-45a9-8463-3a6d4c68e0cd
Local pid:
pubs:369757
Source identifiers:
369757
Deposit date:
2013-11-16

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