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Far-infrared synchrotron spectroscopy and torsional analysis of the important interstellar molecule, vinyl alcohol

Abstract:

We report far-infrared spectra (100–600 cm–1) covering the torsional bands of the important interstellar molecule, vinyl alcohol. We observed the fundamental and first two hot bands of syn-vinyl alcohol and the fundamental and first hot band of anti-vinyl alcohol, whose infrared spectrum has not been previously reported. The hot bands for syn-vinyl alcohol were incrementally shifted by ∼40 cm–1 from the fundamental, implying a high degree of anharmonicity in the torsional potential in the vic...

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Publication status:
Published
Peer review status:
Peer reviewed

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Authors


Hudson, RJ More by this author
More by this author
Department:
Oxford, MPLS, Chemistry, Physical & Theoretical Chem
Raston, PL More by this author
Publisher:
American Chemical Society Publisher's website
Journal:
ACS Earth and Space Chemistry Journal website
Volume:
1
Issue:
2
Pages:
70-79
Publication date:
2017-02-13
DOI:
ISSN:
2472-3452
Pubs id:
pubs:702702
URN:
uri:948a7434-ec37-4144-b2c4-55c6b92743e6
UUID:
uuid:948a7434-ec37-4144-b2c4-55c6b92743e6
Local pid:
pubs:702702

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