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SPIRODIKETOPIPERAZINES AT THE ANOMERIC POSITION OF MANNOPYRANOSE - NOVEL N-LINKED GLYCOPEPTIDES INCORPORATING AN ALPHA-AMINO-ACID AT THE ANOMERIC POSITION OF MANNOPYRANOSE

Abstract:
The first synthesis of a spirodiketopiperazine at the anomeric carbon of a pyranose sugar is described; an N-acylated bicyclic amino [2.2.2] lactone provides access to a new class of glycopeptide analogues of pyranoses and determines the anomeric configuration of the spirodiketopiperazine. The mannopyranose may be equilibrated to the more stable furanose form. © 1995.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MSD, Biochemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON LETTERS
Volume:
36
Issue:
45
Pages:
8287-8290
Publication date:
1995-11-06
DOI:
ISSN:
0040-4039
URN:
uuid:9428b60a-fba8-4756-9fb1-e0c27b8da4ec
Source identifiers:
44901
Local pid:
pubs:44901

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