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New titanium borylimido compounds: synthesis, structure and bonding

Abstract:

We report a combined experimental and computational study of the synthesis and electronic structure of titanium borylimido compounds. Three new synthetic routes to this hitherto almost unknown class of Group 4 imide are presented. The double-deprotonation reaction of the borylamine H2NB(NAr'CH)2 (Ar' = 2,6-C6H3 i Pr2) with Ti(NMe2)2Cl2 gave Ti{NB(NAr'CH)2}Cl2(NHMe2)2 which was easily converted to Ti{NB(NAr'CH)2}Cl2(py)3. This compound is an entry point to other borylimides, for example reacti...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/acs.inorgchem.7b01831

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Author
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Clarendon Fund More from this funder
University of Oxford SCG Innovation Fund More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
56
Issue:
17
Pages:
10794–10814
Publication date:
2017-08-24
Acceptance date:
2017-08-09
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pubs id:
pubs:713357
URN:
uri:9379e3ea-16cb-4618-b98d-8ebe2750e573
UUID:
uuid:9379e3ea-16cb-4618-b98d-8ebe2750e573
Local pid:
pubs:713357
Paper number:
17

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