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HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT

Abstract:
The synthesis of the enantiomeric cis-4-(hydroxymethyl)cyclopent-2-ene-1-ols 2 and 3 (R = H) via a highly enantioselective rearrangement of cis-6-oxabicyclo[3.1.0]hexane-3-methanol 4 (R = H) using the dilithium salts of(+)- or (-)-norephedrine is described. © 1994.
Publication status:
Published

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Journal:
TETRAHEDRON-ASYMMETRY
Volume:
5
Issue:
3
Pages:
337-338
Publication date:
1994-03-05
DOI:
EISSN:
1362-511X
ISSN:
0957-4166
URN:
uuid:936357fc-4fc2-421d-b5dc-5af6eda73a1e
Source identifiers:
52150
Local pid:
pubs:52150
Language:
English

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