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Multielement NMR studies of the liquid-liquid phase separation and the metal-to-nonmetal transition in fluid lithium- and sodium-ammonia solutions.

Abstract:

(1)H, (7)Li, (14)N, and (23)Na high resolution nuclear magnetic resonance (NMR) measurements are reported for fluid solutions of lithium and sodium in anhydrous liquid ammonia across the metal-to-nonmetal transition (MNM transition), paying particular attention to the phenomenon of liquid-liquid phase separation which occurs in the composition/temperature region close to the MNM transition. Our results are discussed in terms of the electronic structure of fluid metal-ammonia solutions at low ...

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Publication status:
Published

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Publisher copy:
10.1021/jp404023j

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Spencer, N More by this author
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Journal:
The journal of physical chemistry. B
Volume:
117
Issue:
42
Pages:
13322-13334
Publication date:
2013-10-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:93494ed3-ee20-4da4-af64-b019de957925
Source identifiers:
429187
Local pid:
pubs:429187
Language:
English

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