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Electrolysis in the presence of ultrasound: cell geometries for the application of extreme rates of mass transfer in electrosynthesis

Abstract:

Two types of sonoelectrochemical reactors for preparative synthetic work are suggested and characterized by their performance in the reversible one electron reduction of cobalticenium cations in acetonitrile solution. The dominant effect of ultrasound is to strongly agitate the liquid phase and the corresponding parameters (mass transport coefficients) for the transport at the electrode surface are reported. An upper limit for ultrasound induced mass transport at macroelectrodes an order of m...

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Publication status:
Published

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Publisher copy:
10.1039/a701004d

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Thiemann, T More by this author
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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
10
Pages:
2055-2059
Publication date:
1997-10-05
DOI:
EISSN:
1364-5471
ISSN:
0300-9580
URN:
uuid:932001ce-99e8-4d6c-a3ee-07c3cb8e5201
Source identifiers:
45773
Local pid:
pubs:45773
Language:
English

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