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Journal article

Design and evaluation of nonfluorous CO2-soluble oligomers and polymers.

Abstract:

Ab initio molecular modeling is used to design nonfluorous polymers that are potentially soluble in liquid CO2. We have used calculations to design three nonfluorous compounds meant to model the monomeric repeat units of polymers that exhibit multiple favorable binding sites for CO2. These compounds are methoxy isopropyl acetate, 2-methoxy ethoxy-propane, and 2-methoxy methoxy-propane. We have synthesized oligomers or polymers based on these small compounds and have tested their solubility in...

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Publication status:
Published

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Publisher copy:
10.1021/jp9073812

Authors


Tapriyal, D More by this author
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Journal:
The journal of physical chemistry. B
Volume:
113
Issue:
45
Pages:
14971-14980
Publication date:
2009-11-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:92bb87b4-4420-46f5-ac75-0088d6011b34
Source identifiers:
117485
Local pid:
pubs:117485
Language:
English

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