Journal article icon

Journal article

PHOTOELECTROCHEMICAL REDUCTION OF META-HALONITROBENZENES AND RELATED SPECIES

Abstract:

Dual photo- and electro-chemical activation of m-chloronitrobenzene and m-bromonitrobenzene in acetonitrile solution leads to halide loss through a photo-ECE mechanism. This proceeds via absorption of visible light by the radical anions [X-C6H4NO2].-, which is followed by fragmentation forming the .C6H 4NO2 aryl radical. The latter reacts with the solvent system forming nitrobenzene which is further reduced at the electrode with the generation of [C6H5NO2].-. Reduction of m-iodonitrobenzene l...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/p29950001673

Authors


Expand authors...
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
8
Pages:
1673-1677
Publication date:
1995-08-05
DOI:
EISSN:
1364-5471
ISSN:
1472-779X
URN:
uuid:9285ef6c-6572-4cfe-bf5d-3f128d93b721
Source identifiers:
44834
Local pid:
pubs:44834
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP