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Hydrogen bonds between methanol and the light liquid olefins 1-pentene and 1-hexene: From novel application to fundamental science

Abstract:
We have recently developed a new extraction process for significantly reducing the olefin content in commercial FCC gasoline. To gain insights into the origins of this process , we have investigated the dissolution of the light liquid olefins 1-pentene and 1-hexene in methanol through computer modelling together with NMR spectroscopy. We find two important hydrogen bonding modes for methanol olefin interactions – namely, O-H···π and C-H···O.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/C6CC09545C

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Al-Megren, H More by this author
Aldrees, S More by this author
Al-Kinany, M More by this author
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King Abdulaziz City for Science and Technology More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
53
Issue:
28
Pages:
4026-4029
Publication date:
2017-03-09
Acceptance date:
2017-03-09
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Pubs id:
pubs:685609
URN:
uri:923dd615-6ecb-4b23-b3b3-1688498eb09a
UUID:
uuid:923dd615-6ecb-4b23-b3b3-1688498eb09a
Local pid:
pubs:685609

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