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Photo-electroanalysis: Indirect determination of anthracene using the oxygen reduction in aqueous acetonitrile

Abstract:

A novel method for the photoelectroanalysis of anthracene, as a model compound, is proposed. This technique utilizes a gold electrode in a flowing system of electrolyte air saturated with oxygen. On irradiation of the electrode with UV-vis light there is a reduction in the level of the oxygen four-electron reductive limiting current due to a reaction of the excited state anthracene and oxygen in acetonitrile/water solution. A linear response over four orders of magnitude (10-2 to 10-1 mol dm-...

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Publication status:
Published

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Publisher copy:
10.1002/elan.1140080719

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS More from this journal
Volume:
8
Issue:
7
Pages:
702-705
Publication date:
1996-07-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
Language:
English
Keywords:
Pubs id:
pubs:45203
UUID:
uuid:922b18e2-2b19-4ace-adbf-e9d33fcf115f
Local pid:
pubs:45203
Source identifiers:
45203
Deposit date:
2012-12-19

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