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RATE COEFFICIENT EXPRESSIONS FOR REACTIONS OF MOLECULES IN PI-2 ELECTRONIC STATES AT LOW-TEMPERATURES

Abstract:

Analytical rate coefficient expressions are derived at low temperatures for the fast reactions of a 2Π molecule with each of a structureless ion, a 2Π molecule, and a 1Π molecule. The procedure, based on classical capture theory, involves perturbation theory and simple long-range electrostatic potential terms for the various interactions. The open-shell nature of the reactant molecules is fully considered. The predictions made are contrasted with those quoted previously for the equivalent rea...

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Publication status:
Published

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Publisher copy:
10.1063/1.464635

Authors


WICKHAM, A More by this author
Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
98
Issue:
1
Pages:
420-426
Publication date:
1993
DOI:
ISSN:
0021-9606
URN:
uuid:911d9fe3-fb4d-49eb-a62b-91bde43e5bc4
Source identifiers:
53015
Local pid:
pubs:53015
Language:
English

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