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Cp*TaCl2B4H8: Synthesis, crystal structure and spectroscopic characterization of an air-stable, electronically unsaturated, chiral tantalaborane

Abstract:
Reaction between Cp*TaCl4 (Cp* = η5-C5H5) and BH3·thf at 40 °C yields the pale red electronically unsaturated cluster Cp*TaCl2B4H8 1 which despite having two electrons fewer than the seven pairs required for the observed square pyramidal geometry is stable in air; viewed as a cluster, 1 is the first example of an unsaturated cluster containing a single metal atom; viewed as a chiral 16-electron organometallic complex it is isoelectronic with Cp(C2B9H11)TaCl2 and Cp[(Me3Si)2C2B4H 4]TaCl2.
Publication status:
Published

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Publisher copy:
10.1039/a706483g

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CHEMICAL COMMUNICATIONS More from this journal
Issue:
2
Pages:
207-208
Publication date:
1998-01-21
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
Pubs id:
pubs:46078
UUID:
uuid:90a1784f-4ba9-43c6-894a-5235a4ddd8a5
Local pid:
pubs:46078
Source identifiers:
46078
Deposit date:
2012-12-19

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