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Cation and spin ordering in the n=1 Ruddlesden-Popper phase La2Sr2LiRuO8

Abstract:

The synthesis and characterization of a polycrystalline sample of the n = 1 Ruddlesden-Popper phase La2Sr2LiRuO8 are reported. X-ray and neutron diffraction show that the six-coordinate sites are occupied by 1:1 ordered xy layers of Li:Ru, and the nine-coordinate sites are occupied by 1:1 ordered layers of La:Sr; a low concentration (7.4%, 9.8% respectively) of anti-site defects was detected on each sublattice. These layers stack in an ordered sequence along z, resulting in an orthorhombic un...

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Publication status:
Published

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Publisher copy:
10.1021/cm049053w

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
CHEMISTRY OF MATERIALS
Volume:
16
Issue:
22
Pages:
4257-4266
Publication date:
2004-11-02
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
URN:
uuid:8fe7d01a-eaea-4a86-bf48-e49559faf83f
Source identifiers:
39241
Local pid:
pubs:39241
Language:
English

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