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Imidotitanium Tris(pyrazolyl)hydroborates: Synthesis, Solution Dynamics, and Solid-State Structure.

Abstract:

Reaction of [Ti(NBu(t))Cl(2)(py-Bu(t))(2)] (1; py-Bu(t) = 4-tert-butyl pyridine) with 1 equivalent of K[Tp(Me2)], K[Tp(Pri)] or K[Tp(Pri,Br)] affords the corresponding complexes [Tp(Me2)Ti(NBu(t))Cl(py-Bu(t))] (2), [Tp(Pri)Ti(NBu(t))Cl(py-Bu(t))] (3), and [Tp(Pri,Br)Ti(NBu(t))Cl(py-Bu(t))] (4), respectively, which are the first examples of imido Group 4 tris(pyrazolyl)hydroborates [Tp(Me2) = tris(3,5-dimethylpyrazolyl)hydroborate; Tp(Pri) = tris(3-isopropylpyrazolyl)hydroborate; Tp(Pri,Br) = ...

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Publication status:
Published

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Publisher copy:
10.1021/ic9510674

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry More from this journal
Volume:
35
Issue:
4
Pages:
1006-1012
Publication date:
1996-02-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Pubs id:
pubs:51026
UUID:
uuid:8fb564d8-b2f8-4cc2-97d3-1b960008492f
Local pid:
pubs:51026
Source identifiers:
51026
Deposit date:
2012-12-19

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