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Synthesis and characterization of amide-borohydrides: New complex light hydrides for potential hydrogen storage

Abstract:

The reactions xLiNH2 + (1 - x)LiBH4 and xNaNH2 + (1 - x)NaBH4 have been investigated and new phases identified. The lithium amide-borohydride system is dominated by a body centred cubic compound of formula Li4BH4(NH2)3. In the sodium system, a new hydride of approximate composition Na2BH4NH2 has been identified with a primitive cubic structure and lattice parameter a ≈ 4.7 Å. The desorption of gases from the two amide-borohydrides on heating followed a similar pattern with the relative propor...

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Publication status:
Published

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Authors


Chater, PA More by this author
Anderson, PA More by this author
Prendergast, JW More by this author
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Volume:
446
Pages:
350-354
Publication date:
2007-10-31
DOI:
ISSN:
0925-8388
URN:
uuid:8f7feea2-34dc-4469-8890-4c825a66c7ca
Source identifiers:
40592
Local pid:
pubs:40592

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