Journal article
A stereoselective total synthesis of (±)-tormesol
- Abstract:
- A general strategy for the synthesis of both trans/syn- and trans/anti-sphenolobane diterpenes has been developed, which utilizes an intramolecular ester enolate alkylation (IEEA) as a key step. A stereoselective total synthesis of (±)-tormesol (1), an unusual trans/syn-sphenolobane diterpene, was accomplished in 18 steps in 4.1% overall yield from readily available aldehyde 16. © 2011 Elsevier Ltd. All rights reserved.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Publisher copy:
- 10.1016/j.tet.2011.09.022
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Authors
Funding
Bibliographic Details
- Publisher:
- Elsevier Publisher's website
- Journal:
- TETRAHEDRON Journal website
- Volume:
- 67
- Issue:
- 51
- Pages:
- 10017-10025
- Publication date:
- 2011-12-23
- DOI:
- EISSN:
-
1464-5416
- ISSN:
-
0040-4020
- Source identifiers:
-
216332
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:216332
- UUID:
-
uuid:8f16ffd1-a581-449d-b61e-8f906c55dce5
- Local pid:
- pubs:216332
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2011
- Notes:
- © 2011 Published by Elsevier Ltd. The full text of this article is not available in ORA. You may be able to access the article via the publisher copy link above.
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