- Abstract:
- A general strategy for the synthesis of both trans/syn- and trans/anti-sphenolobane diterpenes has been developed, which utilizes an intramolecular ester enolate alkylation (IEEA) as a key step. A stereoselective total synthesis of (±)-tormesol (1), an unusual trans/syn-sphenolobane diterpene, was accomplished in 18 steps in 4.1% overall yield from readily available aldehyde 16. © 2011 Elsevier Ltd. All rights reserved.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Publisher copy:
- 10.1016/j.tet.2011.09.022
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- Publisher:
- Elsevier Ltd. Publisher's website
- Journal:
- TETRAHEDRON Journal website
- Volume:
- 67
- Issue:
- 51
- Pages:
- 10017-10025
- Publication date:
- 2011-12-23
- DOI:
- EISSN:
-
1464-5416
- ISSN:
-
0040-4020
- URN:
-
uuid:8f16ffd1-a581-449d-b61e-8f906c55dce5
- Source identifiers:
-
216332
- Local pid:
- pubs:216332
- Language:
- English
- Keywords:
- Copyright date:
- 2011
- Notes:
- © 2011 Published by Elsevier Ltd. The full text of this article is not available in ORA. You may be able to access the article via the publisher copy link above.
Journal article
A stereoselective total synthesis of (±)-tormesol
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