- Abstract:
-
The Herzfeld criterion for an insulator-to-metal transition is recast here to predict the critical concentration (n(cr)) for metallization of a solution having a solute more polarizable than the host solvent. The Clausius-Mossotti relation applied to the pure solvent shows that its polarizability and density affect n(cr) only through the pure solvent refractive index or high-frequency dielectric constant. The critical concentration is reduced by solvent polarizability but increased by positiv...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ja993644j
-
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- Journal:
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume:
- 122
- Issue:
- 21
- Pages:
- 5092-5099
- Publication date:
- 2000-05-31
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- URN:
-
uuid:8ee5baed-dc65-4f50-b664-bde796e443c0
- Source identifiers:
-
46276
- Local pid:
- pubs:46276
- Language:
- English
- Copyright date:
- 2000
Journal article
Metallization of alkali anions in condensed phases
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