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Alkyl dehydrogenation in iridium tri-cyclopentyl phosphines

Abstract:

The iridium cyclooctadiene complex incorporating a tricyclopentyl phosphine ligand (PCyp₃), Ir(η²:η²-C₈H₁₂) (PCyp₃)Cl, has been prepared. Removal of the chlorine from this complex using Na[BAr₄f][Arf = C₆H₃(CF₃)₂] in CH₂Cl₂/arene solvent results in dehydrogenation (C-H activation followed by β-H transfer) of one of the alkyl phosphine rings and formation of the complexes [Ir(η⁶-C₆H₅X){PCyp₂(η²-C₆H₇)}] [BAr₄f] (X=H,F) which contain a hybrid phosphine-alkene lig...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.ica.2009.03.004

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Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author
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Publisher:
Elsevier Publisher's website
Journal:
Inorganica Chimica Acta Journal website
Volume:
363
Issue:
3
Pages:
574-580
Publication date:
2010-02-05
DOI:
ISSN:
0020-1693
URN:
uuid:8ec7ef0b-79f0-41c7-be56-fad5ab727bd8
Local pid:
ora:3638

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