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Journal article

Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes.

Abstract:
Efficient catalysts for the dehydrocoupling or dehydropolymerisation of H(3)B·NMe(x)H((3-x)) (x = 1, 2) have been developed by variation of the P-Rh-P angle in {Rh(Ph(2)P(CH(2))(n)PPh(2))}(+) fragments (n = 2-5).
Publication status:
Published

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Publisher copy:
10.1039/c0cc05460g

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemical Communications More from this journal
Volume:
47
Issue:
13
Pages:
3763-3765
Publication date:
2011-04-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
Pubs id:
pubs:118025
UUID:
uuid:8e81709c-fc7f-4358-b477-c15909b1a03b
Local pid:
pubs:118025
Source identifiers:
118025
Deposit date:
2012-12-19

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