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SYNTHESIS OF PERMETHYLINDENYL COMPLEXES OF THE EARLY TRANSITION-METALS - CRYSTAL-STRUCTURES OF TI(ETA(5)-C(9)ME(7))CL-3 AND ZR(ETA(5)-C(9)ME(7))(2)CL-2

Abstract:: Addition of 1-(trimethylsilyl)heptamethylindene (C9Me7SiMe3) to a suspension of the anhydrous halides MCl4 (M = Ti, Zr, and Hf) in THF gives the half-sandwich complexes M(η5-C9Me7)Cl3 (M = Ti, Zr, and Hf) in good yield. Ti(η5-C9Me7)2Cl3 crystallizes in the centrosymmetric orthorhombic space group Pbca with a = 16.875(4) Å, b = 14.706(3) Å, c = 13.781(3) Å, V = 3420 Å3, Z = 8, R = 0.047, and Rw = 0.049. The Ti-C distances range from 2.352(4) to 2.400(4) Å with a mean value of 2.370(5) Å and ar...
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APA Style

Ohare, D., Murphy, V., Diamond, G., Arnold, P., & Mountford, P. (1994). SYNTHESIS OF PERMETHYLINDENYL COMPLEXES OF THE EARLY TRANSITION-METALS - CRYSTAL-STRUCTURES OF TI(ETA(5)-C(9)ME(7))CL-3 AND ZR(ETA(5)-C(9)ME(7))(2)CL-2. ORGANOMETALLICS, 13(12), 4689–4694.

MLA Style

Ohare, D., et al. “SYNTHESIS OF PERMETHYLINDENYL COMPLEXES OF THE EARLY TRANSITION-METALS - CRYSTAL-STRUCTURES OF TI(ETA(5)-C(9)ME(7))CL-3 AND ZR(ETA(5)-C(9)ME(7))(2)CL-2.” ORGANOMETALLICS, vol. 13, no. 12, 1994, pp. 4689–94.

Chicago Style

Ohare, D, V Murphy, G Diamond, P Arnold, and P Mountford. 1994. “SYNTHESIS OF PERMETHYLINDENYL COMPLEXES OF THE EARLY TRANSITION-METALS - CRYSTAL-STRUCTURES OF TI(ETA(5)-C(9)ME(7))CL-3 AND ZR(ETA(5)-C(9)ME(7))(2)CL-2.” ORGANOMETALLICS 13 (12): 4689–94.
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Publisher copy:: 10.1021/om00024a014

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+ Ohare, D More by this author

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+ Murphy, V More by this author

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+ Diamond, G More by this author

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+ Arnold, P More by this author

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+ Mountford, P More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

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Author

Bibliographic Details

Journal:: ORGANOMETALLICS
Volume:: 13
Issue:: 12
Pages:: 4689-4694
Publication date:: 1994-12-01
DOI:: 10.1021/om00024a014
EISSN:: 1520-6041
ISSN:: 0276-7333

Item Description

Language:: English
Pubs id:: pubs:52002
UUID:: uuid:8e7fb092-18d2-4803-a76f-767c563f2bb5
Local pid:: pubs:52002
Source identifiers:: 52002
Deposit date:: 2012-12-19

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Copyright date:: 1994

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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