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Mechanochromic MOF nanoplates: spatial molecular isolation of light-emitting guests in a sodalite framework structure

Abstract:

Mechanochromic materials have a wide range of promising technological applications, such as photonics based sensors and smart optoelectronics. Examples of mechanochromic metal-organic framework (MOF) materials, however, are still relatively uncommon in the literature. Herein, we present a previously undescribed Guest@MOF system, comprising “Perylene@ZIF 8” nanoplates which will undergo a reversible 442 nm ⇌ 502 nm photoemission switching subject to a moderate level of mechanically-induced pre...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1039/C7NR09730A

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More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Engineering Science
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Engineering Science
Oxford college:
Balliol College
ORCID:
0000-0002-5770-408X
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Nanoscale Journal website
Volume:
10
Issue:
8
Pages:
3953-3960
Publication date:
2018-01-24
Acceptance date:
2018-01-18
DOI:
ISSN:
2040-3364
Pubs id:
pubs:821234
URN:
uri:8e561642-f3ae-43c2-83e9-3bfce2b08fdd
UUID:
uuid:8e561642-f3ae-43c2-83e9-3bfce2b08fdd
Local pid:
pubs:821234

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