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Hydropnictination Reactions of Carbodiimides and Isocyanates with Protonated Heptaphosphide and Heptaarsenide Zintl Ions

Abstract:

By following a similar procedure to that employed for the synthesis of [HP7]2- (1), the synthesis and characterization of the hydrogenheptaarsenide dianion [HAs7]2- (2) was achieved. Building on previous research that has shown that [HP7]2- can react with carbodiimides to yield amidine-functionalized cluster anions [P7C(NHR)(NR)]2-, we have found that the analogous hydroarsination reactions are also possible by reaction of 2 with RC=N=CR to yield [As7C(NHR)(NR)]2- [R = Dipp (3), iPr (4) and C...

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Publication status:
Published

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Publisher copy:
10.1002/ejic.201301011

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
Wiley
Journal:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY More from this journal
Volume:
2014
Issue:
10
Pages:
1660-1668
Publication date:
2014-04-01
DOI:
EISSN:
1099-0682
ISSN:
1434-1948
Language:
English
Keywords:
Pubs id:
pubs:462057
UUID:
uuid:8e3e7da1-dd4d-42ce-acf1-1b21b4917dfe
Local pid:
pubs:462057
Source identifiers:
462057
Deposit date:
2014-06-17

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