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Simulation of square wave voltammetry: Reversible electrode processes

Abstract:

A general approach is developed for the numerical simulation of square wave voltammetry (SWV) at uniformly accessible electrodes, based on the backward implicit method. Appropriate transformations of both the spatial coordinate normal to the electrode surface and of the time variable are developed and are shown to lead to efficient and accurate simulations. The method is applied to the modeling of electrochemically reversible processes, and the results predicting the variation of peak height,...

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Publication status:
Published

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Publisher copy:
10.1021/jp9901390

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY B
Volume:
103
Issue:
25
Pages:
5289-5295
Publication date:
1999-06-24
DOI:
EISSN:
1520-5207
ISSN:
1089-5647
URN:
uuid:8e3d252e-6389-426d-8cd9-b49626f5f306
Source identifiers:
37089
Local pid:
pubs:37089
Language:
English

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