Journal article
Cyclic Voltammetry of the EC' Mechanism at Hemispherical Particles and Their Arrays: The Split Wave
- Abstract:
-
The EC′ (catalytic) mechanism, (1) A + e- ⇌ B; (2) B + X → K2 A + P, in which the reduction of X to P is mediated by the A/B redox couple, is studied at a regularly distributed array of hemispherical particles on a planar surface using simulated cyclic voltammetry. It is assumed that the supporting surface itself is not electroactive and therefore the electron transfer in process (1) occurs exclusively on the surface of the particles. Two-dimensional finite difference simulations are performe...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- JOURNAL OF PHYSICAL CHEMISTRY C
- Volume:
- 115
- Issue:
- 22
- Pages:
- 11204-11215
- Publication date:
- 2011-06-09
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
Item Description
- Language:
- English
- Pubs id:
-
pubs:159287
- UUID:
-
uuid:8e196134-8694-4652-ac72-8a8c725c615b
- Local pid:
- pubs:159287
- Source identifiers:
-
159287
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2011
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