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Elucidation of the electrochemical oxidation pathway of ammonia in dimethylformamide and the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Abstract:

The direct electrochemical oxidation of ammonia has been examined in both the organic solvent dimethylformamide (DMF) and the room temperature ionic liquid 1-ethyl-3- methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)2]. The corresponding voltammetric responses have been shown to be similar in each solvent with a broad oxidative wave occurring upon the introduction of ammonia to the solution and the appearance of a new reductive wave following the oxidation. The oxidative reacti...

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Publication status:
Published

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Publisher copy:
10.1002/elan.200302910

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Journal:
ELECTROANALYSIS
Volume:
16
Issue:
11
Pages:
888-896
Publication date:
2004-06-01
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
Source identifiers:
39081
Language:
English
Keywords:
Pubs id:
pubs:39081
UUID:
uuid:8dfe7d6d-e040-486b-94f9-2b58e0bc53db
Local pid:
pubs:39081
Deposit date:
2012-12-19

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