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MECHANISM OF A SOLID-LIQUID INTERFACIAL REACTION - THE REACTION OF AN AQUEOUS-SOLUTION OF AN AROMATIC AMINE WITH CYANURIC CHLORIDE

Abstract:: The reaction between solid cyanuric chloride and an aromatic amine, N,N-dimethyl-p-phenylenediamine (DMPA) in aqueous solution is studied using the channel flow cell method in which a constant geometric area of solid is exposed to solution. It is shown that reaction occurs via the dissolution of the solid (with a constant flux of material being released into solution) followed by homogeneous coupling to the amine in parallel with hydrolysis of cyanuric chloride. Kinetic parameters for the pro...
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Publication status:: Published

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APA Style

Compton, R., Harding, M., Atherton, J., & Brennan, C. (1993). MECHANISM OF A SOLID-LIQUID INTERFACIAL REACTION - THE REACTION OF AN AQUEOUS-SOLUTION OF AN AROMATIC AMINE WITH CYANURIC CHLORIDE. JOURNAL OF PHYSICAL CHEMISTRY, 97(18), 4677–4682.

MLA Style

Compton, R., et al. “MECHANISM OF A SOLID-LIQUID INTERFACIAL REACTION - THE REACTION OF AN AQUEOUS-SOLUTION OF AN AROMATIC AMINE WITH CYANURIC CHLORIDE.” JOURNAL OF PHYSICAL CHEMISTRY, vol. 97, no. 18, 1993, pp. 4677–82.

Chicago Style

Compton, R, M Harding, J Atherton, and C Brennan. 1993. “MECHANISM OF A SOLID-LIQUID INTERFACIAL REACTION - THE REACTION OF AN AQUEOUS-SOLUTION OF AN AROMATIC AMINE WITH CYANURIC CHLORIDE.” JOURNAL OF PHYSICAL CHEMISTRY 97 (18): 4677–82.
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Publisher copy:: 10.1021/j100120a020

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+ Compton, R More by this author

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+ Harding, M More by this author

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+ Atherton, J More by this author

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+ Brennan, C More by this author

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Bibliographic Details

Journal:: JOURNAL OF PHYSICAL CHEMISTRY
Volume:: 97
Issue:: 18
Pages:: 4677-4682
Publication date:: 1993-05-06
DOI:: 10.1021/j100120a020
EISSN:: 1541-5740
ISSN:: 0022-3654

Item Description

Language:: English
Pubs id:: pubs:44093
UUID:: uuid:8dde8f8d-5149-48d9-a519-5778c39c9c78
Local pid:: pubs:44093
Source identifiers:: 44093
Deposit date:: 2012-12-19

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Copyright date:: 1993

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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