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MECHANISM OF A SOLID-LIQUID INTERFACIAL REACTION - THE REACTION OF AN AQUEOUS-SOLUTION OF AN AROMATIC AMINE WITH CYANURIC CHLORIDE

Abstract:

The reaction between solid cyanuric chloride and an aromatic amine, N,N-dimethyl-p-phenylenediamine (DMPA) in aqueous solution is studied using the channel flow cell method in which a constant geometric area of solid is exposed to solution. It is shown that reaction occurs via the dissolution of the solid (with a constant flux of material being released into solution) followed by homogeneous coupling to the amine in parallel with hydrolysis of cyanuric chloride. Kinetic parameters for the pro...

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Publication status:
Published

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Publisher copy:
10.1021/j100120a020
Journal:
JOURNAL OF PHYSICAL CHEMISTRY More from this journal
Volume:
97
Issue:
18
Pages:
4677-4682
Publication date:
1993-05-06
DOI:
EISSN:
1541-5740
ISSN:
0022-3654
Language:
English
Pubs id:
pubs:44093
UUID:
uuid:8dde8f8d-5149-48d9-a519-5778c39c9c78
Local pid:
pubs:44093
Source identifiers:
44093
Deposit date:
2012-12-19

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