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Conversion of Li2FeSbO5 to the Fe(III)/Fe(V) phase LiFeSbO5 via topochemical lithium extraction

Abstract:

Reaction between Na2FeSbO5 and LiNO3 at 300 °C yields the metastable phase Li2FeSbO5 which is isostructural with the sodium “parent” phase (space group Pbnaa = 15.138(1) Å, b = 5.1440(3) Å, c = 10.0936(6) Å) consisting of an alternating stack of Li2Fe2O5 and Li2Sb

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.chemmater.2c00156

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Somerville College
Role:
Author
ORCID:
0000-0002-6248-2063
Publisher:
American Chemical Society
Journal:
Chemistry of Materials More from this journal
Volume:
34
Issue:
5
Pages:
2468-2475
Publication date:
2022-02-24
Acceptance date:
2022-02-16
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
Language:
English
Keywords:
Pubs id:
1242326
Local pid:
pubs:1242326
Deposit date:
2023-01-16

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