- Abstract:
-
Measurements on the diffusion coefficient of the neutral molecule N,N,N',N'-tetramethyl-para-phenylenediamine and the radical cation and dication generated by its one- and two-electron oxidation, respectively, are reported over the range 298-348 K in both acetonitrile and four room temperature ionic liquids (RTILs). Data were collected using single and double potential step chronoamperometry at a gold disk electrode of micrometer dimension, and analysed via fitting to the appropriate analytic...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1002/cphc.200400549
-
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- Journal:
- Chemphyschem : a European journal of chemical physics and physical chemistry
- Volume:
- 6
- Issue:
- 3
- Pages:
- 526-533
- Publication date:
- 2005-03-05
- DOI:
- EISSN:
-
1439-7641
- ISSN:
-
1439-4235
- URN:
-
uuid:8d74970e-5380-44b2-aa9a-b3b597b848fe
- Source identifiers:
-
33045
- Local pid:
- pubs:33045
- Language:
- English
- Keywords:
- Copyright date:
- 2005
Journal article
A comparative electrochemical study of diffusion in room temperature ionic liquid solvents versus acetonitrile.
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