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Preparation of Sr7Mn4O13F2 by the topotactic reduction and subsequent fluorination of Sr7Mn4O15.

Abstract:
The topotactic reduction and subsequent fluorination of Sr7Mn4O15 yields a phase of composition Sr7Mn4O13F2. Characterization of this phase utilizing powder neutron diffraction and 19F NMR shows that the fluoride ions are located on a single anion site, the same crystallographic site that is vacant in the reduced intermediate Sr7Mn4O13.
Publication status:
Published

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Publisher copy:
10.1021/ic800066g

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
47
Issue:
12
Pages:
5212-5217
Publication date:
2008-06-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
34230
Language:
English
Pubs id:
pubs:34230
UUID:
uuid:8d305ca1-e40f-4360-89c2-e8a7224ecbc1
Local pid:
pubs:34230
Deposit date:
2012-12-19

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