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Toward the Understanding of Modulation in Molecular Materials: Barluenga's Reagent and its Analogues.

Abstract:

Investigations into the phase transition of Barluenga's reagent revealed a transient incommensurately modulated phase; the structures are presented herein. To understand the origin of the modulated phase and the chemistry that can affect it, analogues of Barluenga's reagent were synthesized and studied. In this context, the halogen and anion can easily be exchanged. Studying different analogues led to the development of the Ratchet Model to describe the behavior in the solid state leading to ...

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Publication status:
Published

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Publisher copy:
10.1021/cg500983s

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
American Chemical Society
Journal:
CRYSTAL GROWTH and DESIGN More from this journal
Volume:
14
Issue:
12
Pages:
6294-6301
Publication date:
2014-12-01
DOI:
EISSN:
1528-7505
ISSN:
1528-7483
Language:
English
Pubs id:
pubs:500908
UUID:
uuid:8cd75852-af07-4f58-85f2-08034f996ae2
Local pid:
pubs:500908
Source identifiers:
500908
Deposit date:
2015-01-02

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