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Electrode kinetics at carbon electrodes and the density of electronic states.

Abstract:
Marcus-Hush theory relates the rate of electron transfer to the density of electronic states of the electrode material. Through use of a carbon microelectrode--for which the density of states is expected to vary as a function of potential--this predication is validated for graphitic materials by measurement of a variety of outer-sphere redox systems.
Publication status:
Published

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Publisher copy:
10.1039/c2cc30165b

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Chemical communications (Cambridge, England)
Volume:
48
Issue:
27
Pages:
3294-3296
Publication date:
2012-04-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:8ca913a9-2087-4510-b7bf-2a04f109ecfb
Source identifiers:
312738
Local pid:
pubs:312738
Language:
English

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