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A nickel-alkyl bond in an inactivated state of the enzyme catalyzing methane formation.

Abstract:: (Chemical Equation Presented) The spin reveals all: Electron paramagnetic resonance spectroscopy reveals the formation of a nickel-alkyl bond in the active site of methyl-coenzyme M reductase (MCR), the key enzyme of methanogenesis, when active MCRred1 reacts with the irreversible inhibitor 3-bromopropane sulfonate to form the MCRBPS species. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.

Publication status:: Published

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APA Style

Hinderberger, D., Piskorski, R., Goenrich, M., Thauer, R., Schweiger, A., Harmer, J., & Jaun, B. (2006). A nickel-alkyl bond in an inactivated state of the enzyme catalyzing methane formation. Angewandte Chemie (International Ed. in English), 45(22), 3602–3607.

MLA Style

Hinderberger, D., et al. “A Nickel-Alkyl Bond in an Inactivated State of the Enzyme Catalyzing Methane Formation.” Angewandte Chemie (International Ed. in English), vol. 45, no. 22, 2006, pp. 3602–07.

Chicago Style

Hinderberger, D, R Piskorski, M Goenrich, R Thauer, A Schweiger, J Harmer, and B Jaun. 2006. “A Nickel-Alkyl Bond in an Inactivated State of the Enzyme Catalyzing Methane Formation.” Angewandte Chemie (International Ed. in English) 45 (22): 3602–7.
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Publisher copy:: 10.1002/anie.200600366

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+ Hinderberger, D More by this author

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+ Piskorski, R More by this author

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+ Goenrich, M More by this author

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+ Thauer, R More by this author

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+ Schweiger, A More by this author

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Bibliographic Details

Journal:: Angewandte Chemie (International ed. in English)
Volume:: 45
Issue:: 22
Pages:: 3602-3607
Publication date:: 2006-05-01
DOI:: 10.1002/anie.200600366
EISSN:: 1521-3773
ISSN:: 1433-7851

Item Description

Language:: English
Keywords:: Electron Spin Resonance Spectroscopy

Methane

Oxidoreductases

Nickel

Catalysis

Alkanesulfonic Acids
Pubs id:: pubs:326041
UUID:: uuid:8c8cf47d-605f-4960-a55f-7aad8298b897
Local pid:: pubs:326041
Source identifiers:: 326041
Deposit date:: 2012-12-19

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Copyright date:: 2006

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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