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Generation of cationic two-coordinate group-13 ligand systems by spontaneous halide ejection: remarkably nucleophile-resistant (dimethylamino)borylene complexes.

Abstract:
Spontaneous ejection of chloride from a three-coordinate boron Lewis acid can be effected by employing very electron rich metal substituents and leads to the formation of a sterically unprotected terminal (dimethylamino)borylene complex that has a short metal-boron bond and remarkable resistance to attack by nucleophilic and protic reagents.
Publication status:
Published

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Publisher copy:
10.1021/ja101192e

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Journal:
Journal of the American Chemical Society
Volume:
132
Issue:
13
Pages:
4586-4588
Publication date:
2010-04-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:8c2ccb9d-af23-439b-ac81-a3d202c44be5
Source identifiers:
51493
Local pid:
pubs:51493
Language:
English

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