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Novel cobalt complex as an efficient catalyst for converting CO2 into cyclic carbonates under mild conditions

Abstract:

Based on the ligand H2dpPzda (1), a novel cobalt complex [Co(H2dpPzda)(NCS)2]·CH3OH(2) has been synthesized and characterized. The Complex 2 exhibited excellent catalytic performance for converting CO2 into cyclic carbonates under mild conditions. For propylene oxide (PO) and CO2 synthesis of propylene carbonate (PC), the catalytic system showed a remarkable TOF as high as 29,200 h−1. The catalytic system also showed broad substrate scope of epoxide. Additionally, the catalyst could be recycl...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.3390/catal9110951

Authors


Publisher:
MDPI
Journal:
Catalysts More from this journal
Volume:
9
Issue:
11
Article number:
951
Publication date:
2019-11-14
Acceptance date:
2019-11-07
DOI:
EISSN:
2073-4344
Language:
English
Keywords:
Pubs id:
1075131
Local pid:
pubs:1075131
Deposit date:
2020-08-12

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