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On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity.

Abstract:
We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.
Publication status:
Published

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Publisher copy:
10.1039/c4cc06094f

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications
Volume:
50
Issue:
82
Pages:
12281-12284
Publication date:
2014-10-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Language:
English
Pubs id:
pubs:484065
UUID:
uuid:8c11ad77-45ff-40cb-a5c6-135e5ec7d57a
Local pid:
pubs:484065
Source identifiers:
484065
Deposit date:
2014-09-18

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