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THE ANODIC-OXIDATION OF 1,4-DIAMINOBENZENE - AN ELECTRON-SPIN RESONANCE AND ELECTROCHEMICAL STUDY

Abstract:

The electrochemical e.s.r. of 1,4-diaminobenzene, 1,4-diamino-2- chlorobenzene, and 1,4-diamino-2-methylbenzene has been studied in aqueous methanol using an apparatus in which a tube electrode is linked to the e.s.r. cavity. Laminar flow transports species from the electrode into the cavity. The distribution of species in the cavity can be described theoretically and from the variation of e.s.r. signal with current, flow rate, concentration, and pH the protonation and kinetic stability of th...

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Publication status:
Published

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Publisher copy:
10.1039/p29810000825

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Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
5
Pages:
825-829
Publication date:
1981-01-01
DOI:
EISSN:
1364-5471
ISSN:
1472-779X
URN:
uuid:8bdb408e-ede1-4032-89a5-8051c2fb6f38
Source identifiers:
52827
Local pid:
pubs:52827
Language:
English

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