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Mechanochemical approaches towards the in situ confinement of 5-FU anti-cancer drug within MIL-100 (Fe) metal–organic framework

Abstract:
We elucidate two annealing assisted mechanochemical methods to achieve one-pot encapsulation of anti-cancer drug 5-fluorouracil (5-FU) in the iron-based MIL-100 metal–organic framework (MOF). We compare the structural and physicochemical properties of drug@MIL-100 systems derived from in situ manual and vortex grinding, where the former technique exhibits a slower drug release due to stronger guest–host interactions.
Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/d0ce00638f

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
ORCID:
0000-0001-6315-2149
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
ORCID:
0000-0002-5770-408X
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
CrystEngComm Journal website
Volume:
22
Issue:
27
Pages:
4526-4530
Publication date:
2020-06-29
Acceptance date:
2020-06-29
DOI:
EISSN:
1466-8033
Language:
English
Keywords:
Pubs id:
1116200
Local pid:
pubs:1116200
Deposit date:
2020-07-03

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