Journal article icon

Journal article

Light‐induced pulsed EPR dipolar spectroscopy on a paradigmatic hemeprotein

Abstract:

Light-induced pulsed EPR dipolar spectroscopic methods allow the determination of nanometer distances between two paramagnetic sites. Here we employ orthogonal spin labels, one of which is a chromophore triplet state and the other a stable radical to carry out distance measurements in singly nitroxide-labeled human neuroglobin. We demonstrate that Zn-substitution of neuroglobin, to populate the Zn(II) protoporphyrin IX triplet state, makes it possible to perform the light-induced pulsed dipol...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's Version

Actions


Access Document


Files:
Publisher copy:
10.1002/cphc.201900139

Authors


Dal Farra, MG More by this author
Richert, S More by this author
Larminie, C More by this author
Expand authors...
Publisher:
Wiley Publisher's website
Journal:
ChemPhysChem Journal website
Volume:
20
Issue:
7
Pages:
931-935
Publication date:
2019-02-28
Acceptance date:
2019-02-28
DOI:
EISSN:
1439-7641
ISSN:
1439-4235
Pubs id:
pubs:980464
URN:
uri:8b9baa63-ab7f-476c-b1f1-8c28354b3558
UUID:
uuid:8b9baa63-ab7f-476c-b1f1-8c28354b3558
Local pid:
pubs:980464

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP