- Abstract:
-
Cyanide ions are shown to interact with lanthanide complexes of phenacylDO3A derivatives in aqueous solution, giving rise to changes in the luminescence and NMR spectra. These changes are the consequence of cyanohydrin formation, favoured by the coordination of the phenacyl carbonyl group to the lanthanide centre. These complexes display minimal affinity for fluoride and can detect cyanide at <1 µM concentrations. By contrast, lanthanide complexes with DOTAM derivatives display no affinity...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 546.1KB)
-
- Publisher copy:
- 10.1002/anie.201702296
-
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- Grant:
- European Union’s seventh Framework Programme (FP7/2007_2013)/ERC-Advanced Grant Agreement Number 267426
- Publisher:
- Wiley-VCH Verlag Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 56
- Issue:
- 27
- Pages:
- 7783–7786
- Publication date:
- 2017-06-05
- Acceptance date:
- 2017-05-09
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Pubs id:
-
pubs:694170
- URN:
-
uri:8b81fc92-83ff-4b25-bcc5-d94af87c7f6c
- UUID:
-
uuid:8b81fc92-83ff-4b25-bcc5-d94af87c7f6c
- Local pid:
- pubs:694170
- Paper number:
- 27
- Copyright holder:
- WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
- Copyright date:
- 2017
- Notes:
-
Copyright © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley-VCH Verlag at: https://doi.org/10.1002/anie.201702296
Journal article
Lanthanide complexes that respond to changes in cyanide concentration in water
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+ European Research Council
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