Journal article
Lanthanide complexes that respond to changes in cyanide concentration in water
- Abstract:
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Cyanide ions are shown to interact with lanthanide complexes of phenacylDO3A derivatives in aqueous solution, giving rise to changes in the luminescence and NMR spectra. These changes are the consequence of cyanohydrin formation, favoured by the coordination of the phenacyl carbonyl group to the lanthanide centre. These complexes display minimal affinity for fluoride and can detect cyanide at <1 µM concentrations. By contrast, lanthanide complexes with DOTAM derivatives display no affinity...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 546.1KB)
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- Publisher copy:
- 10.1002/anie.201702296
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Authors
Funding
+ European Research Council
More from this funder
Grant:
European Union’s seventh Framework Programme
(FP7/2007_2013)/ERC-Advanced Grant Agreement Number
267426
Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 56
- Issue:
- 27
- Pages:
- 7783–7786
- Publication date:
- 2017-06-05
- Acceptance date:
- 2017-05-09
- DOI:
- EISSN:
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1521-3773
- ISSN:
-
1433-7851
- Source identifiers:
-
694170
Item Description
- Keywords:
- Pubs id:
-
pubs:694170
- UUID:
-
uuid:8b81fc92-83ff-4b25-bcc5-d94af87c7f6c
- Local pid:
- pubs:694170
- Deposit date:
- 2017-05-11
Terms of use
- Copyright holder:
- WILEY-VCH Verlag GmbH & Co KGaA, Weinheim
- Copyright date:
- 2017
- Notes:
- Copyright © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley-VCH Verlag at: https://doi.org/10.1002/anie.201702296
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