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Thesis

The synthesis and reactivity of cationic terminal borylene complexes

Abstract:

This thesis describes the synthesis, structure/bonding studies and reactivity of cationic terminal borylene complexes. Reactions of the cationic terminal borylene complexes, [CpFe(CO)₂(BNR₂)]⁺[BArf₄]⁻ (R = Cy, ⁱPr) with heteroallenes have been investigated and shown to proceed by initial coordination of the substrate at the electrophilic boron centre. Reaction with isocyanate ultimately forms [CpFe(CO)₂(CNPh)]⁺[BArf₄]⁻ by a net metathesis process. Dicyclohexylcarbodiimide, however, reacts by ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Oxford college:
Queen's College
Role:
Author
More by this author
Division:
MPLS
Department:
Chemistry
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Publication date:
2010
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
UUID:
uuid:8b77a1f2-937a-4476-9dc4-bfebd0f94861
Local pid:
ora:3604
Deposit date:
2010-04-01

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