- Abstract:
-
An electrode surface confined redox group contributes to a substantial potential-dependent interfacial charging that can be sensitively probed and frequency-resolved by impedance-derived capacitance spectroscopy. In utilizing the sensitivity of this charging fingerprint to redox group environment, one can seek to generate derived sensory configurations. Exemplified here through the generation of mixed molecular films comprising ferrocene and antibody receptors to two clinically important targ...
Expand abstract - Publisher copy:
- 10.1021/ac403727h
-
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- Journal:
- Analytical Chemistry
- Volume:
- 86
- Issue:
- 5
- Pages:
- 2559-2564
- Publication date:
- 2014-03-04
- DOI:
- EISSN:
-
1520-6882
- ISSN:
-
0003-2700
- URN:
-
uuid:8b706239-4a31-4247-a029-44e276e58609
- Source identifiers:
-
466707
- Local pid:
- pubs:466707
- Copyright date:
- 2014
Journal article
Label-free capacitive diagnostics: Exploiting local redox probe state occupancy
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