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Insertion of Allenes into the Pd-C Bond of Ortho-Palladated Primary Arylamines of Biological Relevance: Phenethylamine, Phentermine, (L)-Phenylalanine Methyl Ester, and (L)-Tryptophan Methyl Ester. Synthesis of Tetrahydro-3-benzazepines and Their Salts

Abstract:

The previously reported ortho-metalated complexes [Pd(C,N-ArCH 2CRR'NH2-2)(μ-X)]2 derived from phenethylamine (Ar = C6H4, R = R' = H, X = Cl, Br), phentermine (Ar = C6H4, R = R' = Me, X = Cl), (l)-phenylalanine methyl ester (Ar = C6H4, R = H, R' = CO2Me, X = Cl, Br)), and (l)-tryptophan methyl ester (Ar = C 8H5N, R = H, R' = CO2Me, X = Cl) react with various allenes to give (1) the corresponding η3-allyl complexes derived from the insertion of one molecule of the allene into the Pd-C bond, th...

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Publication status:
Published

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Publisher copy:
10.1021/om300928j

Authors


Garcia-Lopez, J-A More by this author
Saura-Llamas, I More by this author
McGrady, JE More by this author
Bautista, D More by this author
Vicente, J More by this author
Journal:
ORGANOMETALLICS
Volume:
31
Issue:
23
Pages:
8333-8347
Publication date:
2012-12-10
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:8b50c307-5739-44af-964f-d396e2a54ee8
Source identifiers:
368146
Local pid:
pubs:368146
Language:
English

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