Journal article
Oxynitride perovskites: Synthesis and structures of LaZrO2N, NdTiO2N, and LaTiO2N and comparison with oxide perovskites
- Abstract:
-
A new oxynitride, LaZrQ2N, has been synthesized by the reaction of a highly reactive X-ray amorphous La2Zr2O7 precursor with flowing ammonia at between 900 and 1000 °C. The white insulating material crystallizes in the GdFeQ3 distorted perovskite structure type with orthorbombic space group Pnma and with a = 5.875 25(5) Å, b = 8.250 31(7) Å, c = 5.810 08(5) Å, and Z = 4, as determined by neutron powder diffraction. A detailed structural analysis of the isostructural NdTiO2N is also reported: ...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/cm010577v
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Authors
Bibliographic Details
- Journal:
- CHEMISTRY OF MATERIALS
- Volume:
- 14
- Issue:
- 1
- Pages:
- 288-294
- Publication date:
- 2002-01-05
- DOI:
- EISSN:
-
1520-5002
- ISSN:
-
0897-4756
- URN:
-
uuid:8b4ce9f1-fa0f-4a52-9b4f-49bdfb080e32
- Source identifiers:
-
38109
- Local pid:
- pubs:38109
Item Description
- Language:
- English
Terms of use
- Copyright date:
- 2002
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